Synthesis and Characterisation of Bis-(chloromethyl) Oxetane, its Homopolymer and Copolymer with Tetrahydrofuran
نویسندگان
چکیده
Bis-(chloromethyl) oxetane (BCMO) was synthesised from pentaerythritol by chlorination, followed by ring closure. It was polymerised using BF 3 -etherate and butanediol system, similarly the BCMO–THF (tetrahydrofuran) copolymer was also synthesised. The monomers and the polymers were characterised by IR, H-NMR and molecular weight. Flame retardant properties of the poly-BCMO were also investigated.
منابع مشابه
Synthesis and Characterization of Acrylic Copolymers of 4-Chloromethyl Styrene with Incorporation of Phthalimide Groups and Amination of Resulted Polymers
4-ChloroMethyl Styrene (CMS) was copolymerized with different monomers such as Methyl MethAcrylate (MMA), Methyl Acrylate (MA), 2-EthylHexyl Acrylate (EHA) by free radical polymerization method at 70 ±1°C using a,a'-Azobis(IsoButyroNitrile) (AIBN) as an initiator. The copolymer compositions were obtained using related 1HNMR spectra and the poly...
متن کاملInvestigation of the Properties of Polyurethane Elastomer Based on Synthesis and Characterization of PTHF-GAP-PTHF Triblock Copolymer
Binder has a key role in the performance of composite propellants. The binders are classified into two neutral and high-energy categories. GAP is one of the most important energetic binders, but it has poor mechanical and thermal properties. The goal of this investigation is to improve the properties of GAP by copolymerizing it with polytetrahydrofuran. New energy triblock copolymer was synthes...
متن کاملMicrophase separation through competitive hydrogen bonding in self-assembled A-b-B/C diblock copolymer/homopolymer complexes.
We present a study of microphase separation induced by competitive hydrogen bonding in A-b-B/C diblock copolymer/homopolymer complexes where the diblock copolymer A-b-B is immiscible and the homopolymer C can interact unequally with both A and B blocks through hydrogen bonding. A model system containing poly(2-vinyl pyridine)-block-poly(methyl methacrylate) (P2VP-b-PMMA) and poly(4-vinyl phenol...
متن کاملSynthesis, Characterisation and Flocculation Properties of Carboxymethyl Cellulose-g Acrylamide
Graft copolymers of acrylamide on carboxymethyl cellulose (d.s 0.4-0.5) were prepared by the use of ceric ion, ceric ion/reductant molecule initiator systems in aqueous medium. The graft copolymers were characterized by IR spectroscopy. The extent of graft copolymerisation was measured in terms of grafted chains as a function of both ceric ion and ceric ion/reductant molecule concentrations. It...
متن کاملSynthesis and Thermal Properties of Novel Biodegradable ABCBA Pentablock Copolymers from Poly (Ethylene glycol), L-Lactide and p-Dioxanone
In this work, new biodegradable ABCBA type pentablock copolymers with different mole ratio of L-lactide and PPDO-b-PEG-b-PPDO triblock copolymer were synthesized and characterized. In the first step, PPDO-b-PEG-b-PPDO triblock copolymer was synthesized via a ring-opening polymerization of P-DiOxanone (PDO) monomer with Poly (Ethylene Glycol) (P...
متن کامل